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Chapter 7 – Energy and Energy Balances The concept of energy conservation as expressed by an energy balance equation is central to chemical engineering calculations. Similar to mass balances studied previously, a balance on energy is crucial to solving many problems. _____ System

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Performing Multi-Phase Mass and Energy Balances (Separations) Performing Multi - Phase Mass and Energy Balances Using thermodynamics in mass / energy balance problems means that additional equations are available for solving the required unknowns. How can VLE calculations be used in mass balance applications?

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Energy balance, constant pressure The energy balance for the constant-pressure case follows from Equation 6.15 CP dT dt … HRknA in which CP …VRˆCP is the total constant-pressure heat capacity. For an ideal gas, we know from thermodynamics that the two total heat capacities are simply related, CV …CP nR (6.21) 16/139

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Doing a balance on a single stage within a distillation column, or even a group of stages, is much like doing a balance on a single flash drum. For reasons that will become clear in the next section, we typically write our balance equations separately for the region above and below the feed stage.

Energy Balances on Closed Systems A system is closed if mass does not cross the system boundary during the period of time covered by energy balance. Energy balance for a closed system written between two instants of time is ∆U+∆Ek +∆Ep =Q−W ∆Uis change internal energy, ∆Ek is change in kinetic energy and ∆Ep is change in potential

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